The synthesis and characterization of some compounds of titanium(IV) with the formula T&\_,-(ORt), (where x = 2, 3 for X = Cl; x = 1, 2 for X = isopropoxy and ORt = 2,2,2-tri~oroethoxy, OCH,-CFJ and their adducts with a nitrile (CH&N, C,H,-CN) and the alcohol RtOH are reported. Using an acidity scal
Preparation and Reactions of (2-chloroethoxy)- and (2,2,2-trifluoroethoxy)-trichlorotitanium(IV)
β Scribed by Ram Chand Paul; Pratibha Sharma; P.K. Gupta; S.L. Chadha
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 303 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0020-1693
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β¦ Synopsis
The title compounds have been prepared. Infrared spectra of these compounds indicate that titanium is four-coordinate in them. These compounds form complexes of the type Ti(OR)C13~L or 2L (where R = CzH4CI or CzHzF3 and L is monodentate ligand) with various oxygen and nitrogen ligands. The complexes have been characterized by their analyses and infrared spectra.
π SIMILAR VOLUMES
## Abstract The terminal allene C~__Ξ±__~ο£ΎC~__Ξ²__~ bonds of 4vinylideneβ2βoxazolidinone (2) readily undergo [2+2] cycloaddition with a wide variety of terminal alkynes, alkenes, and 1,3βdienes irrespective of their electronic nature under strictly thermal activation conditions (70β100βΒ°C) and provid