Phenyliodonium bis(perfltloroalkanesulfony1) methides PhI'--C(S02"2F)2 (3) were prepared by the reaction of bis(perfluoroa1kanesulfonyl)methanes with diacetoxyiodobenzene. The photochemical reactions of 3 with alkenes, methanol, bromine, and benzene gave the corresponding addition or insertion produ
Preparation and reaction of bis (perfluoroalkanesulfonyl)methyl halides
โ Scribed by Zhu Shi-Zheng; Xu Guo-Lin; Qin Chao-Yue; Xu Yong; Chu Qian-Lk
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 437 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0256-7660
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The reactions of bis[bis(trimethyIsilyl)methyl]germylene (1) and the corresponding stannylene (2) with di-tert-butykliazidosilane gave N-(azidosi-1yl)germanimine (4) and the stannanimine (5) in quantitative yields. The structures have been confirmed by single-crystal X-ray diffraction. Crystal data