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Preparation and reaction of allylamine-rhodium(III) chloride complexes

✍ Scribed by Sawai, Hiroaki; Hirai, Hidefumi


Book ID
126225980
Publisher
American Chemical Society
Year
1971
Tongue
English
Weight
413 KB
Volume
10
Category
Article
ISSN
0020-1669

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Primary, secondary, and tertiary alkylrhodoximes 1 were prepared from alkyl bromides and tosylates 4 and the trans-dichlororhodium complex 3. X-ray crystallography of the previously unknown tert-butylrhodoxime 1 k reveals structural features of this terf-o-alkylrhodium compound. Photochemical homoly