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Chloride exchange with chloro-amine-rhodium(III) and -iridium(III) complexes

โœ Scribed by J. Burgess; K.W. Bowker; E.R. Gardner; F.M. Mekhail


Book ID
115975875
Publisher
Elsevier Science
Year
1979
Weight
230 KB
Volume
41
Category
Article
ISSN
0022-1902

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The synthesis and characterization of heterobimetallic and complexes are formed in nearly quantitative yields by metathesis reactions from the respective homodimeric mixed-valence complexes in which orthometalated [(ppy) 2 MCl] (M = Rh, Ir; ppy = 2-phenylpyridine anion) and compounds. The structures