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Preparation and properties ofphosphito-P(triazenato-N1, N3 mercury compounds and their PPh3 coordinaion complexes

✍ Scribed by Johann Eichbichler; Paul Peringer

Publisher: Elsevier Science
Year: 1981
Tongue: English
Weight: 239 KB
Volume: 54
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)95438-0

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✦ Synopsis

PhSe and Mn(CO)s) have been investigated in the past few years [l-lo] . Interest developed in (i) synthetic aspects (depending on the position of the redistribution equilibrium in the solid state), (ii) the position of the redistribution equilibrium in solution, (iii) ligand exchange processes, (iv) the ambidentate P/O system for compounds involving L, (v) the bonding mode of the triazenato (= triazaallyl) ligands in solution and in the solid state and (vi) monitoring the trans influence. This work deals with synthesis and properties of (EtO)sP(O)HgT, compounds, involving a phosphorus-mercury-nitrogen bond sequence, and their PPh3 coordination complexes.

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