✦ LIBER ✦

The preparation of new manganese(II) isocyanide complexes, MnI2(CNBut)n (n=1, 1.5, 2) and the mixed isocyanide/tertiary-phosphine complex MnI2(PPh3)(CNBut)2. The isolation and X-ray crystallographic characterisation of the MnI/MnII mixed-valence isomeric complexes [Mn(CNBut)6][MnI3(PPh3)] and [Mn(CNBut)5(PPh3)][MnI3(CNBut)]

✍ Scribed by Stephen M. Godfrey; Qing Li Guang; Charles A. McAuliffe; Peter T. Ndifon; Robin G. Pritchard

Publisher: Elsevier Science
Year: 1992
Tongue: English
Weight: 838 KB
Volume: 198-200
Category: Article
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(00)92344-2

No coin nor oath required. For personal study only.

✦ Synopsis

The preparation of new manganese(I1) isocyanide complexes, MnI,(CNBut), (n= 1, 1.5, 2) and the mixed isocyanide/tertiaryphosphine complex Mn12(PPh3)(CNBuf)2. The isolation and X-ray crystallographic characterisation of the Mn'/Mn" mixed-valence isomeric complexes [Mn(CNBu'),][MnI, (PPh,)] and [Mn(CNBut),(PPh,)][MnI,(CNBut)]