Preparation and properties of ZnBr(CF3)·2L — a convenient route for the preparation of CF3I
✍ Scribed by Dieter Naumann; Wieland Tyrra; Birgit Kock; Werner Rudolph; Bernd Wilkes
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 255 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0022-1139
No coin nor oath required. For personal study only.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
Trifluoromethanesulfonic anhydride reacts with superacidic solutions AF/SbF 5 (A = H, D) to form their corresponding salts CF 3 SO 3 A 2 + SbF 6 -, which are protonated forms of trifluoromethanesulfonic acid and CF 3 SO 2 F as by-product. The salts have been characterized by vibrational spectroscopy
Further investigations have shown that ( I ) is also formed on reaction of Hg(CN), or Hg(SCH,), with HP(CF,),, the reaction rate decreasing in the order Hg(CN), > Hg(CH=CH,), > Hg(SCH,), > Hg(CH,),.