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Preparation and properties of two pentacarbonyltungsten complexes of substituted cyclopropenylidenes

✍ Scribed by Y. Kawada; W.M. Jones


Book ID
108354254
Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
402 KB
Volume
192
Category
Article
ISSN
0022-328X

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The complexes [Li (DIME) 2 ][W(CO) 5 L] [L = OCN 2, NCS 3a, [Na(DIME) 2 ][W(CO) 5 N 3 ] (5), [Li(DIME) 2 ][W 2 (CO) 10 (Β΅-H)] (6), and [K(DIME) 2 ][W 2 (CO) 10 (Β΅-CN)] (7) were synthesized in this PPh 2 4, SiMe 2 Ph 8, N(SiMe 3 ) 2 9, CH 2 Ph 10, Si 6 Me 11 11; DIME = diethylene glycol dimethyl ethe