Preparation and properties of some cationic binuclear platinum(I) complexes
โ Scribed by Michael P. Brown; Susan J. Franklin; Richard J. Puddephatt; Mary A. Thomson; Kenneth R. Seddon
- Book ID
- 108347331
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 775 KB
- Volume
- 178
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
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The oxidative addition of XRCN to PtL4 yields cis-and/or trans-F'tX(RCN)L, (X = C1, Br; R = (CHS)~, n = 1, 2, 3; L = PPh,, PPh,CH,, AsPh,). L is readily displaced by more basic phosphines or by a diphosphine. In each case the trans complex is the thermodynamically more stable isomer and cis-lrulzs i
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