Preparation and properties of molybdenum fluoro-bronzes
โ Scribed by J.W. Pierce; H.L. McKinzie; M. Vlasse; A. Wold
- Publisher
- Elsevier Science
- Year
- 1970
- Tongue
- English
- Weight
- 568 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0022-4596
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Three kinds of hydrated potassium bronze, K 0.23 (H 2 O) 0.65 MoO 3.00 (HyK-AD), K 0.23 (H 2 O) 0.43 MoO 3.00 (HyK-H2), and K 0.23 (H 2 O) 0.27 MoO 3.00 (HyK-H1), were obtained from hydrated sodium bronzes by cation exchange. Hydrated potassium bronzes dried under vacuum are of two types. The first,
We succeeded in synthesizing the hydrogen coinserted hydrated potassium molybdenum bronzes (HKBz) with the 8-and 6-coordination structures by a direct new reduction method. By this method, the 8-coordination type was obtained. According to NMR results, the behavior of protons in the 8-coordination t