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Preparation and properties of chlorosulfenyl - aziridines

✍ Scribed by G.L. Gard; M. Hare; A. Lork; R. Mews; W.-D. Stohrer; R. Winter

Book ID
104150468
Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
38 KB
Volume
54
Category
Article
ISSN
0022-1139

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The sterically crowded 2,2,4,4-tetramethyl-3-thioxocyclo-as the Ξ±-chlorosulfenyl chlorides 8 and 12 which yielded corresponding disulfides after treatment with equimolar butanone (7) and its dithio analogue 9 were found to react readily with gaseous chlorine to afford 1:1 and 1:2 adducts, amounts of