Aromatic sulfone ether diamine, bis[4-(4-aminophenoxy)phenyl]sulfone (SED), was prepared by the nucleophilic aromatic substitution of 44'dichlorodiphenylsulphone by p-aminophenolate. The reaction was conducted in the presence of excess potassium carbonate as a weak base, toluene as the dehydrating agent and N-methylpyrrolidone as the dipolar aprotic solvent. SED showed good solubility in common organic solvents, such as dioxan, tetrahydrofuran, butanone and acetone. SED was reacted with maleic anhydride to obtain aromatic sulfone ether bismaleimide, bis[4-(4-maleimidophenoxy)phenyl]sulfone (SEM). The compounds were characterized by FTIR and 'H NMR analysis. Furthermore, copolymer resins of SED with 4,4'-bismaleimidodiphenyl methane (BMI) and SEM were prepared. After curing, crosslinked resins with better thermal stability resulted. The temperature at maximum rate of weight loss (T,,J and the heat-resistant temperature index (TJ in air were found to be 426"C, 208ยฐC and 579"C, 221ยฐC for BMI/SED and SEM/SED resins, respectively. Compared with the corresponding 4,4'-diaminodiphenyl methane (DDM) system, BMI/SED and SEM/SED showed a slight decrease in T,,, and q. SEDmodified BMI/amine resin based glass cloth laminates for printed circuit boards showed higher mechanical properties than those of the corresponding unmodified system. With SED instead of the original amine component in 3-5% weight fraction, the tensile strength, flexural strength and impact strength of the laminates increased markedly. Meanwhile, the stripping strength and weld resistance were also improved by the addition of SED.