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Preparation and properties of alkylpalladium(II) and -platinum(II) alkynyl complexes

โœ Scribed by Yong-Joo Kim; Kohtaro Osakada; Akio Yamamoto

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
413 KB
Volume
452
Category
Article
ISSN
0022-328X

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โœ Renzo Ros; Jacques Renaud; Raymond Roulet ๐Ÿ“‚ Article ๐Ÿ“… 1975 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 457 KB

The oxidative addition of XRCN to PtL4 yields cis-and/or trans-F'tX(RCN)L, (X = C1, Br; R = (CHS)~, n = 1, 2, 3; L = PPh,, PPh,CH,, AsPh,). L is readily displaced by more basic phosphines or by a diphosphine. In each case the trans complex is the thermodynamically more stable isomer and cis-lrulzs i