Phosphino-Aminothiazoline Platinum(II) and Platinum(II)/Gold(I) Complexes: Structural, Chemical and Vapoluminescent Properties
β Scribed by Roberto Pattacini; Carlo Giansante; Paola Ceroni; Mauro Maestri; Pierre Braunstein
- Publisher
- John Wiley and Sons
- Year
- 2007
- Tongue
- English
- Weight
- 601 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0947-6539
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π SIMILAR VOLUMES
The oxidative addition of XRCN to PtL4 yields cis-and/or trans-F'tX(RCN)L, (X = C1, Br; R = (CHS)~, n = 1, 2, 3; L = PPh,, PPh,CH,, AsPh,). L is readily displaced by more basic phosphines or by a diphosphine. In each case the trans complex is the thermodynamically more stable isomer and cis-lrulzs i
## Abstract Stepwise syntheses of monometallic palladium(II) and bimetallic palladium(II)/platinum(II) complexes were carried out in order to measure the metallophilicity of potential tetradentate bis(alkylthio)ylidenemalonato ligands. The reaction of [Pd](SO~4~) ([Pd] = (Me~4~en)Pd; Me~4~en = __N_