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Preparation and Properties of 9-Methylenetricyclo[4.3.0.0 3,8 ]non-4-ene

✍ Scribed by Herb, Thilo; Lange, Holger


Book ID
118047375
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
281 KB
Volume
61
Category
Article
ISSN
0022-3263

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Preparation and Properties of 9-Methylenetricyclo(4.3.0.03,8)non-4ene. -The photoelectron spectrum of the title compound (XII) reveals an energy splitting of the π bands by ∼ =1 eV, which is analyzed with the aid of HF-SCF calculations. A considerable interaction between the central six-membered ri

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## Abstract The synthesis of 2,7,9‐trimethylenetricyclo[4.3.0.0^3,8^]nonane (8), 7,9‐dimethylenetricyclo[4.3.0.0^3,8^]nonan‐2‐one (15), and 2,9‐dimethylenetricyclo[4.3.0.0^3,8^]non‐4‐ene (9) has been achieved. The first key step of the synthesis is a Diels‐Alder reaction. In the reaction sequence a