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ChemInform Abstract: 2,7,9-Trimethylenetricyclo(4.3.0.03,8)nonane and 2,9- Dimethylenetricyclo(4.3.0.03,8)non-4-ene. Synthesis and Properties.

โœ Scribed by R. GLEITER; T. HERB; O. BORZYK; I. HYLA-KRYSPIN

Book ID
112022658
Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
26
Category
Article
ISSN
0931-7597

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2,7,9-trimethylenetricyclo[4.3.0.03,8]no
2,7,9-trimethylenetricyclo[4.3.0.03,8]nonane and 2,9-dimethylenetricyclo[4.3.0.03,8]non-4-ene. Synthesis and properties
โœ Gleiter, Rolf ;Herb, Thilo ;Borzyk, Oliver ;Hyla-Kryspin, Isabella ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 776 KB

## Abstract The synthesis of 2,7,9โ€trimethylenetricyclo[4.3.0.0^3,8^]nonane (8), 7,9โ€dimethylenetricyclo[4.3.0.0^3,8^]nonanโ€2โ€one (15), and 2,9โ€dimethylenetricyclo[4.3.0.0^3,8^]nonโ€4โ€ene (9) has been achieved. The first key step of the synthesis is a Dielsโ€Alder reaction. In the reaction sequence a

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2,7,9-Trimethylenetricyclo[4.3.0.03,8]-non-4-ene
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ChemInform Abstract: Preparation and Pro
ChemInform Abstract: Preparation and Properties of 9-Methylenetricyclo(4.3.0.03,8)non-4-ene.
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Preparation and Properties of 9-Methylenetricyclo(4.3.0.03,8)non-4ene. -The photoelectron spectrum of the title compound (XII) reveals an energy splitting of the ฯ€ bands by โˆผ =1 eV, which is analyzed with the aid of HF-SCF calculations. A considerable interaction between the central six-membered ri