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Preparation and mass spectra of 2,5-diaryl-1,4-dithiins

✍ Scribed by Charles M. Buess; Vernon O. Brandt; R. C. Srivastava; W. Robert Carper


Book ID
112122733
Publisher
Journal of Heterocyclic Chemistry
Year
1972
Tongue
English
Weight
265 KB
Volume
9
Category
Article
ISSN
0022-152X

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## Abstract The ^13^C NMR spectra of eight 2,5‐diaryl‐1,4‐dithiins were recorded and signals were assigned. A linear correlation was observed between the electronegativity of the substituent groups on C‐10,10β€² and the chemical shifts of C‐10,10β€² after applying corrections for the magnetic anisotrop

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Bis(2,4-diaryl-3-thienyl) disulfide was isolated in the thermal decomposition of 2,5-diaryl-1,4-dithiin. The formation of the rearranged product as well as the kinetic data suggest strongly the valence isomerization of 2,5-diaryl-1,4-dithiin in the course of the decomposition.