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Preparation and dynamic properties of some dimeric palladium(I) and platinum(I) complexes

โœ Scribed by Boehm, John R.; Balch, Alan L.

Book ID
127180151
Publisher
American Chemical Society
Year
1977
Tongue
English
Weight
929 KB
Volume
16
Category
Article
ISSN
0020-1669

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The oxidative addition of XRCN to PtL4 yields cis-and/or trans-F'tX(RCN)L, (X = C1, Br; R = (CHS)~, n = 1, 2, 3; L = PPh,, PPh,CH,, AsPh,). L is readily displaced by more basic phosphines or by a diphosphine. In each case the trans complex is the thermodynamically more stable isomer and cis-lrulzs i