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Preparation and decomposition of azo compounds. XLVI. Stereochemistry of eight-membered cyclic azo compounds

โœ Scribed by Overberger, Charles G.; Stoddard, John W.; Yaroslavsky, Carmela; Katz, Hyman; Anselme, J. P.

Book ID
121240945
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
637 KB
Volume
91
Category
Article
ISSN
0002-7863

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trans-azo linkages in eight-, nine-, and
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โœ C.G. Overberger; M.S. Chi; Donald G. Pucci; J.A. Barry ๐Ÿ“‚ Article ๐Ÿ“… 1972 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 197 KB

We wish to report the preparations of the first medium-sized cyclic aso compounds possessing trans-aso linkages, namely, trans-1,2-diaza-1-cyclooctene (A), trans-3,8-dimethyl-trans-1,2-diaza-1-cyclooctene (11, trans-l,Z-diaza-lcyclononene (2) and trans-1,2-diasa-1-cyclodecene (4). Irradiation of o&-