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Preparation and Crystal Structure of the Mercury(I) Molybdate(VI) Hg2Mo5O16

โœ Scribed by Annemarie L. Wessels; Wolfgang Jeitschko


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
256 KB
Volume
128
Category
Article
ISSN
0022-4596

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Subcell and Superstructure of a High-Tem
โœ Thomas J. Mormann; Wolfgang Jeitschko ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› John Wiley and Sons ๐ŸŒ German โš– 331 KB

A new (b-)modification of the mercury molybdate Hg 2 Mo 2 O 7 , thermodynamically stable at temperatures above 390 ยฑ 10 ยฐC, was prepared by solid state reaction of HgO with MoO 2 in sealed silica tubes. Its crystal structure, determined from single-crystal X-ray data, has a very pronounced subcell: