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ChemInform Abstract: Subcell and Superstructure of a High-Temperature (β-) Modification of the Mercury(I) Dimolybdate(VI) Hg2Mo2O7.

✍ Scribed by Thomas J. Mormann; Wolfgang Jeitschko

Publisher
John Wiley and Sons
Year
2001
Weight
35 KB
Volume
32
Category
Article
ISSN
0931-7597

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Subcell and Superstructure of a High-Tem
Subcell and Superstructure of a High-Temperature (β-) Modification of the Mercury(I) Dimolybdate(VI) Hg2Mo2O7
✍ Thomas J. Mormann; Wolfgang Jeitschko 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 331 KB

A new (b-)modification of the mercury molybdate Hg 2 Mo 2 O 7 , thermodynamically stable at temperatures above 390 ± 10 °C, was prepared by solid state reaction of HgO with MoO 2 in sealed silica tubes. Its crystal structure, determined from single-crystal X-ray data, has a very pronounced subcell: