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Preparation and Crystal Structure of Lithium Nitride Chloride Li4NCl

✍ Scribed by Rupert Marx

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
242 KB
Volume
128
Category
Article
ISSN
0022-4596

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✦ Synopsis

In the original work on lithium nitride halogenides (2, 3) the stoichiometry of the title compound was assigned as Li N Cl . My own experiments however show that this composition neither leads to a single-phase reaction product nor is it compatible with the unit cell volume determined for the title compound as will be seen later.

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Preparation and Crystal Structure of Li4
Preparation and Crystal Structure of Li4[TaN3]
✍ R. Niewa; D. A. Zherebtsov; H. Borrmann; R. Kniep πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 German βš– 123 KB πŸ‘ 2 views

The new lithium nitridotantalate(V), Li 4 [TaN 3 ], was prepared by reaction of Li 15 [CrN 4 ] 2 N with the wall of a welded Ta ampoule in the presence of metallic Li at 1470 K. Li 4 [TaN 3 ] forms colourless single crystals (platelets, space group Ibca, No. 73, a Ο­ 491.85(4) pm, b Ο­ 973.59(6) pm, c