𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Preparation and characterization of tris(trimethylsilyl)silyl derivatives of zinc, cadmium, and mercury. X-ray crystal structure of Zn[Si(SiMe3)3]2

✍ Scribed by Arnold, John; Tilley, T. Don; Rheingold, Arnold L.; Geib, Steven J.

Book ID
121198363
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
557 KB
Volume
26
Category
Article
ISSN
0020-1669

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Preparation and characterization of arsi
Preparation and characterization of arsine derivatives: X-ray crystal structures of As (SitBuMe2)3, As (SiMe3)2(SiPh3), Et3Ga Β· As(SiMe3)2(SiPh3), and As(SePh)3
✍ Ryan A. Baldwin; Hamid Rahbarnoohi; Leonidas J. Jones III; Andrew T. McPhail; Ri πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 680 KB

As(SirBuMe,), (1) was prepared by the salt-elimination reaction between (Na/K), As and 'BuMe,SiCI. Mixing LiAs(SiMe,), with Ph,SiCl (1:l) yielded As(SiMe,),(SiPh,) (2) in a good crystalline yield. Reaction of 2 (1:I) with Et,Ga gave the expected Lewis acid-base adduct Et,Ga \* As(SiMe,),(SiPh,) (3).

Synthesis and Characterization of Substi
Synthesis and Characterization of Substituted Benzyl Zinc Derivatives - Molecular Structures of (tmeda) Li-CH (GeMe3)Ph, (tmeda)Zn(CH2Ph)2, (tmeda)Zn[CH(SiMe3)Ph]2, and (tmeda)Zn[CH(SiMe3)Ph]N(H)Si(SiMe3)3
✍ Westerhausen, Matthias ;Wieneke, Michael ;Rademacher, Bernd B. ;Schwarz, Wolfgan πŸ“‚ Article πŸ“… 1997 πŸ› Wiley (John Wiley & Sons) 🌐 English βš– 772 KB

## Abstract The reaction of lithium phenyl(trimethylsilyl)methanide with phenyl(trimethylsilyl)methylzinc chloride‐tmeda in the presence of tmeda yields the addition product, a bis(tmeda)‐lithium dialkylchlorozincate. The elimination of lithium chloride leads to the formation of a tmeda adduct of b