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Preparation and characterization of silver nanoparticles with dendrimers as templates

✍ Scribed by Lei Jin; Shi-Ping Yang; Hui-Xia Wu; Wei-Wei Huang; Qi-Wei Tian


Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
480 KB
Volume
108
Category
Article
ISSN
0021-8995

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✦ Synopsis


Abstract

In this study, crystal silver nanoparticle clusters, prepared by the reduction of AgNO~3~ in the presence of third‐to‐sixth‐generation dendrimers with a trimesyl core, were characterized with ultraviolet–visible spectroscopy, transmission electron microscopy, and energy‐dispersive X‐ray spectroscopy. The results showed that the particle size of the silver nanoparticles was considerably affected by the generation of the dendrimers as well as the dendrimer concentration. When the concentration ratios of Ag^+^ to the third‐to‐sixth‐generation dendrimers were all 4 : 1, the average diameters of the obtained particles were 6.7, 6.0, 5.2, and 4.3 nm, respectively. The data from high‐resolution transmission electron microscopy and electron diffraction indicated that the particles belonged to a simple cubic crystal structure. © 2008 Wiley Periodicals, Inc. J Appl Polym Sci 2008


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