A new hydrated phosphate of magnesium with a layered structure was prepared hydrothermally under mild conditions. Provided it is not heated beyond \(200^{\circ} \mathrm{C}\), this solid undergoes reversible dehydrationrehydration with the layered structure remaining intact. The as-prepared precursor
Preparation and Characterization of a New Tl-1222 Layered Cobaltite
✍ Scribed by Sébastien Courjault; Jean-Pierre Doumerc; Patrice Dordor; Jean-Claude Grenier; Paul Hagenmuller; Michel Pouchard
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- German
- Weight
- 124 KB
- Volume
- 628
- Category
- Article
- ISSN
- 0372-7874
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A new layered cuprate with the composition LiI 3 Bi 2 Sr 2 Ca Cu 2 O 8 has been synthesized by the reaction of Bi 2 Sr 2 CaCu 2 O 8 with lithium iodide under an atmosphere of iodine at 300°C. The new cuprate is pale green and lamellar and crystallized in a tetragonal cell with the lattice parameters