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Preparation and characterisation of tris-μ-[bis(diphenylphosphino)methane]diplatinum(0)

✍ Scribed by Martin C. Grossel; Michael P. Brown; Charles D. Nelson; Ahmad Yavari; Elena Kallas; Roger P. Moulding; Kenneth R. Seddon


Book ID
108347097
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
212 KB
Volume
232
Category
Article
ISSN
0022-328X

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Tris­[μ-bis­(di­phenyl­phosphino)­methan
✍ Wu, Mei-Mei ;Qin, Yong-Hai 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 198 KB

The title " 3 -Cl dicapped trisilver compound, [Ag 3 Cl 2 -(C 25 H 22 P 2 ) 3 ][SbF 6 ]Á2CH 2 Cl 2 , exhibits distorted trigonal bipyramidal coordination with two " 3 -Cl atoms at the apices. The Ag I atoms are four-coordinated and exhibit a tetrahedral geometry.