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Preparation and analysis of ε-caprolactam and ε-thiocaprolactam platinue(II) and rhodium(III) complexes

✍ Scribed by P. Dini; J.C.J. Bart; E. Santoro; G. Cum; N. Giordano


Book ID
114040697
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
622 KB
Volume
17
Category
Article
ISSN
0020-1693

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Copolyesteramides—II. Anionic copolymers
✍ I. Goodman; R.N. Vachon 📂 Article 📅 1984 🏛 Elsevier Science 🌐 English ⚖ 656 KB

The N-sodiocaprolactam-catalysed anionic polymerisation of e-caprolactam is activated by e-caprolactone which itself acts as a comonomer, yielding copolyesteramides. At lower temperatures and lower catalyst concentrations, copolymerisation of the lactone is favoured over that of lactam; higher tempe