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Prenylation of olefins in nitromethane

โœ Scribed by M. Julia; C. Schmitz

Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
346 KB
Volume
42
Category
Article
ISSN
0040-4020

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In a recent attempt to add t-butyl hypochlorite to olefins such as styrene and l-hexene in nitromethane, we were surprised to find that the exclusive products of these rapid reactions are chloronitromethane (ClCHaNO =,I) and t-butyl alcohol in nearly quantitative yield. This reaction is outlined in