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Preferential Solvation Effects on the Kinetics and Thermodynamics of Oxidation of Anilines by Chromium(VI)

✍ Scribed by Bhuvaneshwari, D. S.; Elango, K. P.


Book ID
120441412
Publisher
Oldenbourg Wissenschaftsverlag
Year
2006
Tongue
German
Weight
433 KB
Volume
220
Category
Article
ISSN
0942-9352

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Preferential solvational effects on the
✍ A. Thirumoorthi; D. S. Bhuvaneshwari; K. P. Elango πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 145 KB

## Abstract Imidazolium fluorochromate (IFC) oxidation of 11 meta‐ and para‐substituted benzylamines, in varying mole fractions of benzene/2‐methylpropan‐2‐ol binary mixtures, is first order in IFC and acid and zero order in substrate. The Hammett correlation yielded a U‐shaped curve, indicating a