Two mechanisms for the predissociation of the C 2X: state of N$ ar8 discussed -the accidentai mechanism nnd a direct, homogeneous process C -f B 'c:. The matrix elements for the latter channel are dominated by a contribution from the nuclear kinetic energy operator, containing a Fran&-Condon integra
Predissociation rates in the B2Σ− state of CH
✍ Scribed by Jorge Luque; David R Crosley
- Book ID
- 103667207
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 827 KB
- Volume
- 206
- Category
- Article
- ISSN
- 0301-0104
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Highly correlated MRCI electronic wavefunctions are used to calculate the potential energy functions, the nonadiabatic and the spin-orbit coupling elements for the B 2 R À g and neighboring states of the O þ 2 ion. The results are employed in calculations of the spectroscopic constants and the spin-
This work summarizes experimental results from recent ion-dip spectroscopy studies of CaCl and from previously unpublished optical-optical double-resonance work with specific regard to predissociation processes of 2 ⌺ ϩ Rydberg states in the low n\* (n\* ϭ 7, IP Ϫ E n\* ϭ 2240 cm Ϫ1 ) region. A sing