The I B 2 (lieu+) state of CS2 at 210 nm was studied using jet-cooled laser-induced fluorescence and dispersed spectra. The lifetime of the IB2(I]~+ ) state at 210 nm was deduced from the transition linewidth to be 4.4 ps. Hot bands of photofragment CS (A q-l,-X ~E + ) transitions up to v" = 6 were
Predissociating resonances of Cs2 — Theory and experiment
✍ Scribed by Sungyul Lee; Bongsoo Kim; Keitaro Yoshihara
- Book ID
- 112008619
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1997
- Tongue
- English
- Weight
- 695 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0372-8323
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📜 SIMILAR VOLUMES
A collinear model for predissociation of linear triatomic molecules is presented. A very steep repulsive potential for CS (A) + S is obtained by fitting the experimental results from the dissociation of CS2 at various excitation energies. Qualitative agreement has also been obtained for the rotation
Metastnble transitions in CS$ leading to S' + CS and CS++ S under electron impact on CS2 are reported. The predissociation processes able to explain the occurrence of these metastablc transitions are discussed. An interpretation of mrne fast dissociation processes is suggested.