✦ LIBER ✦

Model calculations for the predissociative excitation of CS2

✍ Scribed by Konrad T. Wu

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 607 KB
Volume: 140
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80411-6

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✦ Synopsis

A collinear model for predissociation of linear triatomic molecules is presented. A very steep repulsive potential for CS (A) + S is obtained by fitting the experimental results from the dissociation of CS2 at various excitation energies. Qualitative agreement has also been obtained for the rotational energy distribution of the product fragment. The role of the interfragment effect in determining the CS (A) vibrational distributions is discussed.

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