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Charge exchange of O2+ with Cs: spectroscopy and predissociation pathways for the Πg Rydberg states of O2

✍ Scribed by W.J. Van Der Zande; W. Koot; J.R. Peterson; J. Los

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 572 KB
Volume: 140
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(87)80810-2

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✦ Synopsis

Electron capture by keV 0: (X *ITS) ions from Cs atoms yields predominantly the 'II, and 'II, Rydberg states of 02, which subsequently predissociate. Through the use of translational spectroscopy on the neutral product atoms, we have located a number ofvibrational levels of these states and determined the dissociation channels. Furthermore we have observed competition between diabatic and adiabatic behaviour in the dissociating channels.

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