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Prediction of the effect of the geometric phase on product rotational state distributions and integral cross sections

โœ Scribed by Yi-Shuen Mark Wu; Aron Kuppermann


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
803 KB
Volume
201
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


The effect of the geometric phase induced by the conical intersection between lhe two lowest electronic states of the H+Hs system on product rotational state distributions and integral cross sections is investigated. This effect is shown to significantly change these distributions and the para-to-ortho and ortho-to-para integral cross sections for energies above I .8 eV. In addition, the results are in qualitative agreement with the experimentally measured distnbutions for the D+ Hz reaction. They predict that under appropnate conditions the geometric phase effect may be significant in the many systems that display conical intersections.


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