Dcparrrrwnr uf Cixrmistr> . Statr\_ford Unil ersirj . Smnford. Calijornia 9J305. US.4 Kecrnsd 15 \_aprrl 1963: in find1 form 31 May 19S3 The effect of reagent rotation on the product vibrstional state distribution is reported for the reaction Ca('S) + W(S lx+." = 1.J) -Cal'(S"+, u'.J') + II( An infr
Prediction of the effect of the geometric phase on product rotational state distributions and integral cross sections
โ Scribed by Yi-Shuen Mark Wu; Aron Kuppermann
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 803 KB
- Volume
- 201
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The effect of the geometric phase induced by the conical intersection between lhe two lowest electronic states of the H+Hs system on product rotational state distributions and integral cross sections is investigated. This effect is shown to significantly change these distributions and the para-to-ortho and ortho-to-para integral cross sections for energies above I .8 eV. In addition, the results are in qualitative agreement with the experimentally measured distnbutions for the D+ Hz reaction. They predict that under appropnate conditions the geometric phase effect may be significant in the many systems that display conical intersections.
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