Prediction of the concentration dependence of diffusion coefficients of polymers in solution
β Scribed by J. W. Qian; Alfred Rudin
- Publisher
- John Wiley and Sons
- Year
- 1989
- Tongue
- English
- Weight
- 413 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0021-8995
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π SIMILAR VOLUMES
New correlations, based on the rough hard-sphere theory and an extensive literature database, were developed for the determination of the binary difision coeficients of liquid and solid solutes in supercritical solvents. The correlations were tested to predict 107 solute-solvent systems with good re
## Abstract The freeβvolume theory of diffusion is used to predict the effect of the glass transition on the concentration dependence of the solvent selfβdiffusion coefficient at constant temperature. The theoretical prediction is in agreement with experimental data. Β© 2003 Wiley Periodicals, Inc.