✦ LIBER ✦

Prediction of binary diffusion coefficients of solutes in supercritical solvents

✍ Scribed by Chao-Hong He

Publisher: American Institute of Chemical Engineers
Year: 1997
Tongue: English
Weight: 354 KB
Volume: 43
Category: Article
ISSN: 0001-1541
DOI: 10.1002/aic.690431107

No coin nor oath required. For personal study only.

✦ Synopsis

New correlations, based on the rough hard-sphere theory and an extensive literature database, were developed for the determination of the binary difision coeficients of liquid and solid solutes in supercritical solvents. The correlations were tested to predict 107 solute-solvent systems with good results. The input data required for the correlations are the solute molecular weight, temperature, density and the solvent basic properties (molecular weight, critical volume, and critical pressure).

📜 SIMILAR VOLUMES

Prediction of mutual diffusion coefficie

Prediction of mutual diffusion coefficients for polymer–solvent systems

✍ J. S. Vrentas; C. M. Vrentas 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 93 KB 👁 2 views

A method of predicting diffusion coeffic

A method of predicting diffusion coefficients of solutes at infinite dilution

✍ R. F. Fedors 📂 Article 📅 1979 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 218 KB 👁 1 views

Prediction of solvent-diffusion coeffici

Prediction of solvent-diffusion coefficient in polymer by a modified free-volume theory

✍ W. H. Jiang; R. Han 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 190 KB 👁 1 views

Several versions of free-volume theory have been proposed to correlate or predict the solvent diffusion coefficient of a polymer/solvent system. The quantity of free volume is usually determined by the Williams-Landel-Ferry (WLF) equation from viscosity data of the pure component in these theories.

Solute–solvent and solvent–solvent inter

Solute–solvent and solvent–solvent interactions in binary solvent mixtures. Part 8. The ET(30) polarity of binary mixtures of formamides with hydroxylic solvents

✍ Koit Herodes; Ivo Leito; Ilmar Koppel; Martí Rosés 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 87 KB 👁 1 views

Solvent effects on the binary mixtures of amides with alcohols and water were investigated by means of Reichardt's E T (30) solvatochromic indicator. E N T parameters of binary solvent mixtures of formamide, N-methylformamide and N,N-dimethylformamide with water, methanol, propan-2-ol, 2-methylpropa

Computer-Aided Estimation of Diffusion C

Computer-Aided Estimation of Diffusion Coefficients in Non-Solvent/Polymer Systems

✍ George D. Verros; Nikolaos A. Malamataris 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 215 KB 👁 2 views

Application of corresponding states prin

Application of corresponding states principles for prediction of self-diffusion coefficients in liquids

✍ Mohammad R. Riazi; Thomas E. Daubert 📂 Article 📅 1980 🏛 American Institute of Chemical Engineers 🌐 English ⚖ 427 KB 👁 1 views

## Abstract A corresponding states approach has been used successfully to correlate reduced self‐diffusivity of pure liquids with reduced temperature and acentric factor. In addition, dimensional analysis techniques have been used to accurately relate viscosity, normal boiling point and temperature