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Precision Emission and Absorption Spectroscopy of the Oxygen Atmospheric Bands (b1Σg+–X3Σg−) from Fourier Transform Spectroscopy

✍ Scribed by Alexander J. Phillips; Frank Peters; Peter A. Hamilton

Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
104 KB
Volume
184
Category
Article
ISSN
0022-2852

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✦ Synopsis

The oxygen b 1 S / g -X 3 S 0 g electronic spectrum (the atmospheric system) has been recorded at high resolution in both emission and absorption on the same Fourier transform spectrometer but with independent calibration methods used in each case. After correction for the known pressure shift of the transitions, excellent agreement is achieved between the data sets recorded in this work, allowing significant errors to be identified within and between previous data sets. Molecular constants appropriate to the low pressure limit are determined from these new data for this important transition.

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