Practical synthesis of alkoxyamine initiators for living radical polymerization
✍ Scribed by Bongjin Moon; Minhyuk Kang
- Publisher
- The Polymer Society of Korea
- Year
- 2005
- Tongue
- English
- Weight
- 853 KB
- Volume
- 13
- Category
- Article
- ISSN
- 1598-5032
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The synthesis and examination of different functionalized (2,2,6,6‐tetramethyl‐1‐piperidinyloxy free radical) TEMPO‐containing alkoxyamine initiators for nitroxide‐mediated radical polymerization of styrene are reported. Initiators with ester and carbonate functional groups were synthes
## Abstract Mn(salen)Cl was applied as a low‐cost catalyst for the formation of alkoxyamines from nitroxides and substituted styrenes. These “unimolecular initiators” for nitroxide‐mediated radical polymerization (NMRP) were synthesized using 2,2,6,6‐tetramethyl‐1‐piperidine‐1‐oxyl and 2,2,5‐trimet