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Practical Synthesis of 2-Keto-3-deoxy- d -glycero- d -galactononulosonic Acid (KDN)

✍ Scribed by Crich, David; Navuluri, Chandrasekhar


Book ID
127223623
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
764 KB
Volume
13
Category
Article
ISSN
1523-7060

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Some derivatives of 3-deoxy-d-glycero-d-
✍ Serge David; Annie Malleron; Bertrand CavayΓ© πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 English βš– 696 KB

Treatment of a solution of 3-deoxy-o-glycero-D-galacto-non-2-ulosonic (ICDN) in 11 N aqueous hydrochloric acid with an excess of ethanethiol gave in 52% yield the diethyl dithioacetal of the corresponding l,Clactone, which was further characterized as its peracetate. With 1,3\_propanedithiol, only o