ChemInform Abstract: Reaction Products from Fischer′s Methylation of 3-Deoxy-D-glycero-D- galacto-2-nonulosonic Acid (KDN).
✍ Scribed by T. KAI; X.-L. SUN; M. TANAKA; H. TAKAYANAGI; K. FURUHATA
- Book ID
- 112035109
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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A Novel Glycosylation of 3-Deoxy-D-glycero-D-galacto-2-nonulosonic Acid (KDN) via in situ Pyranose-Furanose Rearrangement. -The title glycosylation is examined in more detail. A proposed mechanism for the ring contracted KND-derivative (V) is discussed. It is noteworthy that all yields are lower if
The reaction of the peracetate methyl esters of N-acetylneuraminic acid (Neu5Ac), 3-deoxyq~glycero-D-galacto-2-nonulosonic acid (Kdn), and 3-deoxy-D-manno-2-octulosonic acid (Kdo) with trimethylsilyl trifluoromethanesulfonate (CF3SO3SiMe 3) has been reinvestigated. We have found that the choice of s