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Pourbaix-type diagram of Fe(III) and Fe(II) phenanthroline complexes

✍ Scribed by Laura Galicia; Ignacio Gonzalez; Yunny Meas; Jorge G. Ibañez

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
386 KB
Volume
35
Category
Article
ISSN
0013-4686

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✦ Synopsis

A potential (E,tpH diagram has been derived for the Fe(IIItFe(II)-1, IO-phenanthrohne system m sulphurlc acid medmm The stab&y of [Fe(IIItl, IO-phenanthrohne], [Fe(IIkl, lo-phenanthrohne] [Fe(IIItsulphate] and [Fe(IIksulphate] complexes discussed With the ald of this diagram, several experlmental results obtamed here and others pubhshed elsewhere are analysed

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## Abstract 3‐3′‐Benzylidenebis[4‐hydroxycoumarin] or 4‐nitro,3‐3′‐benzylidenebis[4‐hydroxycoumarin] or 4‐methoxy,3‐3′‐benzylidenebis[4‐hydroxycoumarin] and their complexes with Cu(II), Fe(II) and Fe(III) were synthesized and characterized using ^1^H‐NMR, ^13^C‐NMR, IR spectra, electronic spectra,