𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Potooxygenation of nitroaromatic compounds. Catalytic effects in the reaction of molecular oxygen with nitrobenzyl derivatives.

✍ Scribed by Peter Wan

Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
268 KB
Volume
26
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

The photooxygenation reaction of several nitroaromatic compounds (1 -4) in aqueous solution is described, the mechanism of reaction is believed to involve photogenerated nitrobenzyl carbanions.

The base-catalyzed oxygenation of organic compounds (eq 1) has been extensively employed in organic synthesis and the mechanism reasonably well-understood 192 . In these reactions, strong bases (e.g., cont. KOH, potassium t-butoxide, NaH, etc.) are usually employed due to B O2 R-CH3 __) R-CH; -R-CH2-O-O--/ product(s)

πŸ“œ SIMILAR VOLUMES

Applications of the photochemical reacti
Applications of the photochemical reaction of iodoheterocyclic derivatives with aromatic compounds in the synthesis of new singlet oxygen sensitizers
✍ Maurizio D'Auria πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 496 KB

Study of the photochemical coupling reaction between 2-iodo-5-nitrothiophene and indolyl derivatives indicated that the coupling reaction occurs on the C-2 position of indole to give products showing absorptions in the visible region. The photochemical reaction between iodoheterocyclic derivatives a

Kinetics of the reactions of singlet mol
Kinetics of the reactions of singlet molecular oxygen (O21Ξ”g) with organic compounds in the gas phase
✍ Robert E. Huie; John T. Herron πŸ“‚ Article πŸ“… 1973 πŸ› John Wiley and Sons 🌐 English βš– 662 KB

## Abstract The reactions of singlet molecular oxygen (O~2~^1^Ξ”~g~) with a series of organic compounds have been studied in the gas phase at 298Β°K. The concentration of singlet molecular oxygen was determined by titration with 2,5‐dimethylfuran. The titration technique was checked using a photoioni