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Potentiometric investigation of the stability of palladium(II) complex of pralidoxime chloride in aqueous solution

✍ Scribed by K. Karljiković-Rajić; B. Stanković

Publisher: Elsevier Science
Year: 1990
Tongue: English
Weight: 279 KB
Volume: 8
Category: Article
ISSN: 0731-7085
DOI: 10.1016/0731-7085(90)80107-z

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✦ Synopsis

The formation of a complex between palladium(II) chloride and pralidoxime chloride (PAM-2Cl) has been studied by means of potentiometric pH measurements. The real stability constant of the complex in aqeous medium of ionic strength 0.3 M (KCl) at 25.0 degrees C was log Ks = 7.29. This value was close to that (log Ks = 7.02) obtained previously by spectrophotometric methods after appropriate correction with respect to the corresponding value of the acidic constant of PAM-2Cl (pKca = 8.05), which was also determined under the same experimental conditions.

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