PMR studies of palladium(II)-glycyl-L-aspartic acid complexes in aqueous solution
✍ Scribed by H. Kozo̵wski; B. Jeźowska-Trzebiatowska
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 304 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0009-2614
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📜 SIMILAR VOLUMES
The conformation for I : 1 and 1: 2 Pd(II)-Giy-Tyr complexes has been established with the 'H NMR method. A correlation between Au-of the AB glycine proton spectrum and the side-chain bulk of the bidentate Gly-Aspa, Gly-Giua and Gly-Tyr complexes with Pd(I? has been found. This relation corresponds
## Abstract The ^17^O‐NMR. line widths of the enriched amino acids glycine, aspartic acid, glutamic acid and, for comparative reasons, acetic acid were measured in aqueous solution between pH 1 and 14. The ^17^O‐NMR. line‐width maxima of glycine at pH≈︁11 and acetic acid at pH≈︁5 are shown to arise
## Abstract The ^17^O‐NMR. chemical shifts of the enriched amino acids glycine, aspartic acid and glutamic acid were measured in aqueous solution as a function of pH. High magnetic fields are necessary to resolve the α, β‐ and α, γ‐carboxyl resonances of aspartic acid and glutamic acid, respectivel