✦ LIBER ✦

Potentials of electrodes of the second kind at low concentrations of common ion electrolyte—I. General discussion

✍ Scribed by F.G.K. Baucke

Publisher: Elsevier Science
Year: 1972
Tongue: English
Weight: 484 KB
Volume: 17
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(72)90007-2

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✦ Synopsis

In electrochemical cells without transference containing an electrode of the second kind deviations between measured and anticipated cell potentials have often been observed at low common anion electrolyte concentrations, particularly when non-aqueous solvents were employed, The solubility of the sparingly soluble salt is proposed to be the cause, and its effect upon potentials of corresponding electrodes of the second kind at low common anion concentrations is discussed. Electrodes involving salts with negligible and with appreciable complex formation must be distinguished.

📜 SIMILAR VOLUMES

Potentials of electrodes of the second k

Potentials of electrodes of the second kind at low concentrations of common ion electrolyte—II. Quantitative treatment of electrodes with salts with negligible complex formation

✍ F.G.K. Baucke 📂 Article 📅 1972 🏛 Elsevier Science 🌐 English ⚖ 649 KB

The effect of solubility of sparingly soluble salts with negligible complex formation with common anions upon potentials of electrodes of the second kind is treated quantitatively. An expression for the electrode potential as a function of the actual solution composition is given and shows good agre