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Potential energy surfaces of one-way and two-way photoisomerization of olefins

✍ Scribed by Katsumi Tokumaru; Tatsuo Arai

Book ID
108043436
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
841 KB
Volume
65
Category
Article
ISSN
1010-6030

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behave as a boundary case distinguishing between one-way and two-way isomerizations. Introduction of an alkyl group (R=t-Bu) and an aryl group (R=Ph) on the P\_ethylenic carbon leads to the one-way and two-way isomerization, respectively. Their triplet energy surfaces are proposed on the basis of me

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Quantum yields for singlet oxygen [01( 'A,)] production ( QA) were measured on quenching of the triplet states of one-way isomerizing 2-anthrylethylenes by means of the singlet oxygen luminescence technique. The trans triplets of these oletins yielded OZ( 'A,) efficiently through energy transfer. Th