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A new “one-way”-photoisomerizing aromatic olefin: the effect of a fluoranthenyl group on the triplet energy surface

✍ Scribed by Tatsuo Arai; Yasunao Kuriyama; Takashi Karatsu; Hirochika Sakuragi; Katsumi Tokumaru; Shigero Oishi

Book ID
103491608
Publisher
Elsevier Science
Year
1987
Weight
455 KB
Volume
36
Category
Article
ISSN
0047-2670

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Factors distinguishing one-way and two-w
Factors distinguishing one-way and two-way photoisomerization of aromatic olefins. Effects of substituents on triplet energy surfaces of 8-fluoranthenylethylenes
✍ Hideo Furuuchi; Tatsuo Arai; Yasunao Kuriyama; Hirochika Sakuragi; Katsumi Tokum 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 454 KB

behave as a boundary case distinguishing between one-way and two-way isomerizations. Introduction of an alkyl group (R=t-Bu) and an aryl group (R=Ph) on the P\_ethylenic carbon leads to the one-way and two-way isomerization, respectively. Their triplet energy surfaces are proposed on the basis of me