✦ LIBER ✦

Potential dependence of the entropy component of the free-energy of activation in linear free-energy relations for electrode processes

✍ Scribed by B.E. Conway; D.F. Tessier; D. Wilkinson

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 448 KB
Volume: 125
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)87105-6

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✦ Synopsis

Kinetic experiments on proton dtscharge at mercury over a range of temperature show that an important entropy component arises in the linear free-energy relationship for the electrode kmetics, m addition to the potential dependence of the Fermi level.

The entropy effect is attributed to the potenttal dependence of solvent orientation.

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