✦ LIBER ✦

Standard potentials of the silver-silver iodide electrode in aqueous mixtures of ethanol and propan-2-ol at different temperatures. Free energies and entropies of transfer of hydroiodic acid at 25°

✍ Scribed by Kaushik Das; Kumardev Bose; Asim K. Das; Kiron K. Kundu

Publisher: Elsevier Science
Year: 1978
Tongue: English
Weight: 465 KB
Volume: 23
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(78)85041-5

No coin nor oath required. For personal study only.

✦ Synopsis

Standard potentials J@ of the silver-silver iodide electrode in ethanol + water and propan-2-01 + water mixtures have been determined from the emf of the cell Pt, Hz (g, 1 atm)[HI(m), solvent1 AgI-Ag at seven temperatures ranging from 10 to 40" for ethanol and from 5 to 35" for propan-l-01. Free energies AG: and entropies AZ of transfer of HI obtained therefrom have been briefly discussed in the light of ion-solvent interactions and solvent structure.

📜 SIMILAR VOLUMES

Standard potentials of the silver/silver

Standard potentials of the silver/silver-iodide electrode in aqueous mixtures of ethylene glycol at different temperatures and the thermodynamics of transfer of hydrogen halides from water to glycolic media

✍ K.K. Kundu; D. Jana; M.N. Das 📂 Article 📅 1973 🏛 Elsevier Science 🌐 English ⚖ 844 KB

The standard potentials (E") of the silver/silver-iodide electrode in aqueous mixtures of ethylene glycol (containing 10,30,50,70 and 90 wt-o/o glycol) have been determined from emf measurements of the cell Pt, Hl(g, 1 atm)/HOAc(ml), NaOAc(m\*), KI(m,), solvent/AgI/Ag at nine temperatures ranging fr