Experimental studies of the ion yield of the reaction e-+ CF3Cl+CF,Cl-+CF3+ Cl-at low energies, E= O-8 eV and temperatures, T= 300-800 K, yield three effects: (A) A threshold peak, hardly noticeable at 300 K, becomes dominant for T> 700 K. (B) The first apparant (shape) resonance of the precursor io
Potential curves for dissociative electron attachment of CFCl3
β Scribed by Sigrid D. Peyerimhoff; Robert J. Buenker
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 567 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Ab initio hlRD CI potential -es are repur~ed for CKI, aud CFCl; and the results are seen to give quantitsti~e support fu a recent interpremcion of the dkso&tivc electron artschment phenomenon in Iwlocarbons. including the fact that in Cl CI3 its&~& pru~zxs~ occur xxith eaunttilly zero electron impact energies C&xdated rertial IP znd transition energy results;rreako found to tit in quite ueU \viUr correspondiug measttred r4ucs
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Dissociative electron attachment cross-section measurements for the production of O-from CO1 have been performed utiliziig a crossed target-hem-electron-beam collision geometry and a qusdrupole mass spectrometer. The relative flow technique is employed to determine the absolute values of cross secti
Complete active space self-consistent field followed by confguration interaction and relativistic configuration interaction calculations are carried out on the potential energy curves of (XeRb)+ arising from Xe( 'So) +Rb+ ('So), Xef(2P,,2) +Rb(2S,,2), Xe+ ('PI12) +Rb( 'SI12), and Xe\*('P) t Rb+ ('S)